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王万辉副教授
 

 

简介

王万辉,副教授,博士生导师。2007获日本政府奖学金资助,赴日本埼玉大学组攻读博士学位。2011年加入日本产业技术综合研究所(AIST)姬田雄一郎(Himeda Yuichiro)研究组开展博士后研究。2012年到大连理工大学精细化工国家重点实验室、石油与化学工程学院任职,同年入选大连理工大学首届星海骨干人才。目前,在国际知名期刊发表SCI论文10余篇,影响因子之和超过90;参与撰写专著3章节;申请发明专利4项;主持国家自然科学青年基金1项,星海骨干人才基金1项,人才引进基金项目1项。

 

 联系方式

 电话   0427-2631809

 传真   0427-2631809

 电子邮箱地址   Chem_wangwh@dlut.edu.cn

 研究室网页 http:// molcatal.dlut.edu.cn

 

 主要学历

 2004.09-2007.07    济南大学,获硕士学位

 2008.04-2011.03    日本埼玉大学,获博士学位

 2011.05-2014.01    日本产业技术综合研究所 (AIST),特别研究员

 2014.02-now    大连理工大学,副教授、“星海骨干”

 

Research Fields

新能源化学存储、CO2资源化利用、绿色催化

 

已发表的学术论文或著作

 

I.

1.  Wang, W.-H.; Hull, J. F.; Muckerman, J. T.; Fujita, E.;* Himeda, Y.* Second-coordination-sphere and electronic effects enhance iridium(III)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure. Energy & Environmental Science 2012, 5, 7923-7926.

2.  Wang, W.-H.; Xu, S.; Manaka Y.; Suna, Y.; Kambayashi, H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Highly efficient formic acid dehydrogenation using bio-inspired Ir complexes: A deuterium kinetic isotope effect study and mechanistic insight. ChemSusChem, 2014,7, 1976-1983.

3.  Wang, W.-H.; Muckerman, J. T.;* Fujita, E.;* Himeda, Y.* Mechanistic insight through factors controlling effective hydrogenation of CO2 catalyzed by bio-inspired proton responsive iridium(III) complexes. ACS Catalysis, 2013, 3, 856-860.

4.  Wang, W.-H.; Hull, J. F.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Highly Efficient D2 Generation by Dehydrogenation of Formic Acid in D2O through H+/D+ Exchange on Iridium Catalyst: Application to the Synthesis of Deuterated Compounds by Transfer Deuterogenation. Chemistry – A European Journal 2012, 18, 9397-9404.

5.  Wang, W.-H.; Suna, Y.; Himeda, Y.;* Muckerman, J. T.; Fujita, E. Functionalized cyclopentadienyl rhodium(III) bipyridine complexes: Synthesis, characterization, and catalytic application in hydrogenation of ketones. Dalton Transactions, 2013, 42, 9628-9636.

6.  Wang, W.-H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Hydroxyl-substituted pyridine-like N-heterocycles: Versatile ligands in organometallic catalysis. New Journal of Chemistry, 2013, 37, 1860-1866.

7.  Wang, W.-H.; Himeda, Y.; Muckerman, J. T.; Fujita, E.* Interconversion of CO2 and formic acid using bio-inspired catalysts under mild conditions in water. Advances in Inorganic Chemistry, 2014, 66, 189-222.

8.  Manaka Y.; Wang, W.-H.;* Suna, Y.; Kambayashi H.; Muckerman, J. T.; Fujita, E.; Himeda, Y.* Efficient H2 generation from formic acid using an azole complex in water. Catalysis Science & Technology, 2014, 4, 34-37.

9.  Badiei, Y. M.;§ Wang, W.-H.;§ Hull, J. F.; Szalda, D. J.; Muckerman, J. T.;* Himeda, Y.;* Fujita, E.* Cp*Co(III) catalysts with proton-responsive ligands for carbon dioxide hydrogenation in aqueous media. Inorganic Chemistry, 2013, 52, 12576-12586. [§并列第一]

10. Wang, W.-H.; Wang, X.-B.; Kodama, K.; Hirose, T.*; Zhang, G.-Y. Novel chiral ammonium ionic liquids as efficient organocatalysts for asymmetric Michael addition of aldehydes to nitroolefins. Tetrahedron 2010, 66, 4970-4976.

11. Wang, W.-H.; Abe, T.; Wang, X.-B.; Kodama, K.; Hirose, T.*; Zhang, G.-Y. Self-assembled proline-amino thioureas as efficient organocatalysts for asymmetric Michael addition of aldehydes to nitroolefins. Tetrahedron: Asymmetry2010, 21, 2925-2933.

12. Hull, J. F.;* Himeda, Y.;* Wang, W.-H.; Hashiguchi, B.; Periana, R.; Szalda, D. J.; Muckerman, J. T.; Fujita, E.* Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures. Nature Chemistry 2012, 5, 383-388.

13. Lewandowska-Andralojc, A.; Polyansky, D. E.; Wang, C.-H.; Wang, W.-H.; Himeda, Y.; Fujita, E.* Efficient water oxidation with organometallic iridium complexes as precatalysts. Physical Chemistry Chemical Physics 2014, 16, 11976-11987.

14. Suna, Y.; Ertem, M. Z.; Wang, W.-H.; Kambayashi, H.; Manaka, Y.; Muckerman, J. T.; Fujita, E.; Himeda, Y.;* Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes. Organometallics 2014,

II.书 籍 章 节

1.  Wang, W.-H.; Himeda, Y. Recent advances of homogeneous iridium catalysts in aqueous solution. In Iridium: Occurrence, Characteristics and Applications, Fukui, C.; Ono, M. Eds., Nova Science Publishers: New York, 2012, pp39-68.

2.  Wang, W.-H.; Himeda, Y. Recent advances in transition metal-catalysed homogeneous hydrogenation of carbon dioxide in aqueous media. In Hydrogenation, Karamé, I. Ed., InTech Publisher, 2012, pp249-268.

3.  Himeda, Y; Wang, W.-H. Application of carbon dioxide in hydrogen storage: homogeneous hydrogenation of carbon dioxide and dehydrogenation of formic acid. In New and future developments in catalysis: activation of carbon dioxide, Suib, S.L. Ed., Elsevier, 2013, pp171-188.

III.申 请 专 利

o   Himeda, Y.; Wang, W.-H. Catalyst for dehydrogenation of formic acid and their application in generation of H2, D2, and HD. 日本专利申请号2012-15087, 国际专利申请号PCT/JP2013/5160.

o   Himeda, Y.; Wang, W.-H. Catalyst for CO2 hydrogenation and HCO2H dehydrogenation and their application in H2 storage and release. 日本专利申请号2012-62042.

Himeda, Y.; Wang, W.-H.; Manaka Y.; Suna, Y. Hydrogen generation method by catalytic dehydrogenation of formic acid. 日本专利申请号2013-213576.

 

 

 

 

 

 

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